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为提高电石渣的资源化利用,实现以废治废,以改性电石渣为脱硝剂,采用单因素法研究了反应温度、氧含量、NO浓度对电石渣脱硝的影响,并利用响应面分析法优化改性电石渣脱除NO的工艺.探讨各因素对NO脱除率的影响,确定了脱硝最佳工艺条件:反应温度276.81℃、氧含量4.71%、NO浓度559.62 mg/m3.利用回归分析法建立了回归模型,其结果表明:NO浓度对NO脱除率有极显著影响,在最优条件下得到NO脱除率为99.56%.
Abstract:In order to improve the resource utilization of calcium carbide slag and realize waste treating waste with waste, the effects of reaction temperature, oxygen content and NO concentration on the denitrification of calcium carbide slag were studied by single factor method with modified calcium carbide slag as denitrification agent, and the NO removal process of modified calcium carbide slag was optimized by response surface methodology. The effects of various factors on NO removal rate were investigated, and the optimum denitrification conditions were determined as follows: reaction temperature was 276.81℃, oxygen content was 4.71%, and NO concentration was 559.62 mg/m3. The regression model was established by regression analysis method, and the results showed that NO concentration had a significant effect on NO removal rate, and the removal rate of NO was 99.56% under the optimal conditions.
[1] 刘小文,李俊,李加兴,等.烟气脱硝技术综述[J].广州化工,2019,47(24):53-55.
[2] 宋亦伟,段继海,张自生,等.催化氧化NO脱硝催化剂研究进展[J].当代化工,2019,48(10):2424-2427.
[3] 李红霞,薄雯,李春颖,等.烟气脱硝技术研究进展[J].现代化工,2015,35(9):30-33.
[4] 张媛媛,陈晓香,韩松.氮氧化物对大气的污染及处理技术[J].化工管理,2015,(34):129-130.
[5] 张小龙.活性炭纤维负载铜锆金属氧化物催化脱除NO实验研究[D].洛阳:河南科技大学,2015.
[6] 张兴宇.活性炭负载钒铜金属氧化物催化脱除NO实验研究[D].洛阳:河南科技大学,2014.
[7] 童志权,陈焕钦.工业废气污染控制与利用[M].北京:化学工业出版社,1989.
[8] 赵惠富.污染气体NOx的形成和控制[M].北京:科学出版社,1993.
[9] 邢奕.钢铁行业烧结烟气超低排放技术路线研究与实践[C]//2019年全国冶金烧结节能减排关键技术研讨会,武汉,2019:1-30.
[10] WANG H,YUAN B,HAO R L,et al.A critical review on the method of simultaneous removal of multi-air-pollutant in flue gas[J].Chemical Engineering Journal,2019,378:122155.
[11] TONG T,CHEN J J,XIONG S C,et al.Vanadium-density-dependent thermal decomposition of NH4HSO4 on V2O5/TiO2 SCR catalysts[J].Catalysis Science & Technology,2019,9:3779-3787.
[12] DAI Z J,WANG L L,TANG H,et al.Speciation analysis and leaching behaviors of selected trace elements in spent SCR catalyst[J].Chemosphere,2018,207:440-448.
[13] XIE X,LI Y J,LIU C T,et al.HCl absorption by CaO/Ca3Al2O6 sorbent from CO2 capture cycles using calcium looping[J].Fuel Processing Technology,2015,138:500-508.
[14] TAO X,ZHANG G M,ZHANG P Y,et al.Thermo-carbide slag pretreatment of energy plants for enhancing enzymatic hydrolysis[J].Industrial Crops & Products,2018,120:77-83.
[15] 马小龙,杜佩英,张志君,等.电石渣资源化利用进展[J].山东化工,2017,46(19):71-72.
[16] WANG X,LI Y J,ZHANG W,et al.Simultaneous SO2 and NO removal by pellets made of carbide slag and coal char in a bubbling fluidized-bed reactor[J].Process Safety and Environmental Protection,2020,134:83-94.
[17] 李锐,王博涛,贾丽娟,等.改性电石渣干法催化净化工业废气中的NO [J].环境工程学报,2021,15(5):1599-1605.
[18] 李军.半焦负载锰铜吸附剂的制备及其联合脱除烟气中SO2和NO的研究[D].太原:太原理工大学,2018.
[19] 姜慧超,王一迪,赵朝成,等.Cu-ZSM-5催化剂直接催化分解NO的试验研究[J].石油炼制与化工,2015,46(3):43-47.
[20] 唐宇星.负载金属催化剂催化氮氧化物分解研究[D].重庆:重庆科技学院,2017.
[21] 张媛.低温条件下活性焦脱硝性能探索研究[D].北京:煤炭科学研究总院,2018.
[22] 杨加强.黄磷复合矿浆脱除烟气NOx的研究[D].昆明:昆明理工大学,2017.
[23] 李倩,谷华春,辛颖,等.V2O5-WO3/TiO2脱硝催化剂机械强度和孔隙率的响应曲面模型[J].化工学报,2015,66(9):3496-3503.
[24] KONTOGIANNOPOULOS K N,PATSIOS S I,KARABELAS A J.Tartaric acid recovery from winery lees using cation exchange resin:Optimization by Response Surface Methodology[J].Separation and Purification Technology,2016,165:32-41.
[25] JIANG J,CHEN Y P,CAO J Z,et al.Improved Hydrophobicity and Dimensional Stability of Wood Treated with Paraffin/Acrylate Compound Emulsion through Response Surface Methodology Optimization[J].Polymers,2020,12(1):86.
[26] THASAN R,JOON C S,SHIK M I.Novel process for simultaneous removal of NOx and SO2 from simulated flue gas by using a sustainable Ag(I)/Ag(II) redox mediator[J].Environmental Science & Technology,2008,42(19).
基本信息:
中图分类号:X701
引用信息:
[1]娜佩,李慧,王建瑜,等.响应面法优化电石渣脱硝工艺的研究[J].云南民族大学学报(自然科学版),2023,32(03):327-333.
基金信息:
国家自然科学基金(51964046,51968075); 云南省教育厅科学研究基金(2022J0441,2022J0442)
2022-05-11
2022
2022-06-08
2022
2022-06-07
1
2022-06-20
2022-06-20
2022-06-20